Structural, Optical, and Electrical Properties of Pure α-Al2O3 Nanopowders with Add V2O7 and Cu2O by Sol-Gel Method

الخصائص التركيبية والضوئية والكهربائية لمساحيق α-Al2O3 النانوية النقية مع إضافة V2O7 وCu2O بطريقة سوجل

Authors

  • S. Al-Ariki1, M. A. Ali. AL-Mushaki1 and Shakib Moqbel Alsowidy2 كلية التربية - جامعة ذمار

DOI:

https://doi.org/10.60037/edu.v12i19.1641

Keywords:

Structural, Optical, and Electrical Properties; α-Al2O3/VO/CuO; nanopowders

Abstract

This manuscript explored the synthesis and comprehensive characterization of pure α-Al2O3 and (α-Al2O3)8-x(V2O7)20(Cu2O)x at varying molar ratios (x = 1%, 2%, and 3%) in nanopowder form, prepared using the sol-gel method. After subjecting the samples to heat treatment, X-ray diffraction (XRD) revealed their high crystallinity. The crystallite size was calculated using the Scherrer formula, exhibited variations among the samples with pure α-Al2O3 possessing a size of 43.10 nm and the mixed oxide nanopowders falling within the range of 29.54 nm to 34.84 nm. These materials displayed semiconductor characteristics, with band gap values ranging from 3.28 eV to 5.21 eV. Moreover, as the molar concentration of copper increased, electrical conductivity improved, signifying potential applications in systems requiring regulated electrical behavior. These findings highlight the versatility of these materials, offering opportunities for tailored crystallinity, band gap tuning, and controlled electrical properties, making them suitable for diverse technological and scientific applications.

Author Biography

S. Al-Ariki1, M. A. Ali. AL-Mushaki1 and Shakib Moqbel Alsowidy2, كلية التربية - جامعة ذمار

كلية التربية جامعة ذمار

كلية التربية جامعة صنعاء

References

M.A.A. Al-Mushaki, S.A. Al-Ariki, A. Alnehia, Effect of copper oxide (CuO) and vanadium oxide (V2O5) addition on the structural, optical and electrical properties of corundum (α-Al2O3), Sci. Rep. 13 (2023) 16100. https://doi.org/10.1038/s41598-023-43309-1.

W. Shaheen, I.H. Abd El Maksod, Thermal characterization of individual and mixed basic copper carbonate and ammonium metavanadate systems, Journal of alloys and compounds 476 (2009) 366-372.

A. Lashgari, S. Ghamami, M. Golzani, G. Salgado-Morán, L. Mendoza-Huizar, P.M. Romero, Biocidal activity of CuO nanoleaves against AGS cells, S. Aureus, E. Coli, and Micrococcus, Afinidad 75 (2018).

D. Volanti, D. Keyson, L. Cavalcante, A.Z. Simões, M. Joya, E. Longo, J.A. Varela, P. Pizani, A. Souza, Synthesis and characterization of CuO flower-nanostructure processing by a domestic hydrothermal microwave, Journal of Alloys and Compounds 459 (2008) 537-542.

K. Chitrarasu, J.U. Bhanu, R. Dhanabal, A. Chandrabose, P. Thangadurai, Structural evolution and electrical properties of the biphasic compound α-Al2O3: MgAl2O4, Materials Research Bulletin 90 (2017) 244-252.

. S. Al Ariki, Yahya, N.A.A., Al-Ansi, S.A. et al. Synthesis and comparative 22

study on the structural and optical properties of ZnO doped with Ni and Ag 23

nanopowders fabricated by sol gel technique. Sci Rep 11, 11948 (2021). 24

https://doi.org/10.1038/s41598-021-91439-1.

S.P. Patil, L. Jadhav, D.P. Dubal, V. Puri, Characterization of NiO–Al2O3 composite and its conductivity in biogas for solid oxide fuel cell, Materials Science-Poland 34 (2016) 266-274.

P. Prashanth, R. Raveendra, R. Hari Krishna, S. Ananda, N. Bhagya, B. Nagabhushana, K. Lingaraju, H. Raja Naika, Synthesis, characterizations, antibacterial and photoluminescence studies of solution combustion-derived α-Al2O3 nanoparticles, Journal of Asian Ceramic Societies 3 (2015) 345-351.

R. Suresh, K. Giribabu, R. Manigandan, S. Munusamy, S.P. Kumar, S. Muthamizh, A. Stephen, V. Narayanan, Doping of Co into V2O5 nanoparticles enhances photodegradation of methylene blue, Journal of Alloys and Compounds 598 (2014) 151-160.

N. Bajaj, S. Omanwar, Low-temperature stearic acid sol–gel synthesis of α-Al 2 O 3 quantum dots and its optical properties, Journal of Sol-Gel Science and Technology 75 (2015) 1-5.

V. Rajkovic, D. Bozic, M.T. Jovanovic, Effects of copper and Al2O3 particles on characteristics of Cu–Al2O3 composites, Materials & Design 31 (2010) 1962-1970.

A. Sadoun, M. Mohammed, E. Elsayed, A. Meselhy, O.A. El-Kady, Effect of nano Al2O3 coated Ag addition on the corrosion resistance and electrochemical behavior of Cu-Al2O3 nanocomposites, Journal of Materials Research and Technology (2020).

S.C. Das, Characterization of structural, optical and electrical properties of Ni doped ZnO thin films, (2012).

I. Momohjimoh, N. Saheb, M. Hussein, T. Laoui, N. Al-Aqeeli, Electrical conductivity of spark plasma sintered Al2O3–SiC and Al2O3-carbon nanotube nanocomposites, Ceramics International (2020).

V.S. de Souza, H.O. da Frota, E.A. Sanches, Polyaniline-CuO hybrid nanocomposite with enhanced electrical conductivity, Journal of Molecular Structure 1153 (2018) 20-27.

R. Barde, S. Waghuley, dc Electrical conductivity of V2O5-P2O5 binary glassy systems, J. Phys.: Conference Series, 2012, pp. 012019.

S. Islam, G. Lakshmi, A.M. Siddiqui, M. Husain, M. Zulfequar, Synthesis, electrical conductivity, and dielectric behavior of polyaniline/V2O5 composites, International Journal of Polymer Science 2013 (2013).

غلاف العدد التاسع عشر - المجلة العلمية لكلية التربية -جامعة ذمار

Published

10/30/2023 — Updated on 01/02/2024

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How to Cite

S. Al-Ariki1, M. A. Ali. AL-Mushaki1 and Shakib Moqbel Alsowidy2. (2024). Structural, Optical, and Electrical Properties of Pure α-Al2O3 Nanopowders with Add V2O7 and Cu2O by Sol-Gel Method: الخصائص التركيبية والضوئية والكهربائية لمساحيق α-Al2O3 النانوية النقية مع إضافة V2O7 وCu2O بطريقة سوجل. Journal of the Faculty of Education, 12(19), 382–399. https://doi.org/10.60037/edu.v12i19.1641 (Original work published October 30, 2023)

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