((تعيين الخواص الضوئية وقدرة الامتزاز، وكفاءة إعادة استخدام الطين النانوي الطبيعي لإزالة الصبغة المباشرة الأنيونية الملوثة للماء))

المؤلفون

  • محمد علي حسين ضيف الله مؤلف
  • وليد عبده أحمد أحمد مؤلف

DOI:

https://doi.org/10.60037/kjns1w90

الكلمات المفتاحية:

النانوي الماز، الصبغة المباشرة الأنيونية، كفاءة الإزالة، قابلية إعادة استخدام المادة الماز

الملخص

ركزت هذه الدراسة على الخصائص الضوئية وأداء الطين النانوي الطبيعي (مونتموريلونيت( كمادة ماصة لإزالة الصبغة الأيونية المباشرة الحمراء من المحاليل المائية. تم تقييم المواد قبل الامتزاز وبعده بشكل منهجي، باستخدام المجهر الإلكتروني الماسح، مع مطيافية فحص مكونات الطين النانوي (SEM-EDX)، وأكدت تحليلات الأشعة تحت الحمراء (FTIR) وجود تفاعلات متبادلة بين هيكل الطين النانوي وجزيئات الصبغة. كشفت الخصائص الضوئية عن حافة نفاذية حادة عند 288 نانومتر وفجوة نطاق واسعة تبلغ 3.8 إلكترون فولت، ما يدعم استقرار بنية المادة وملاءمتها لعملية الامتزاز. أظهرت تجارب الامتزاز (بالأس الهيدروجيني 7.0، ودرجة حرارة 25 درجة مئوية) أداءً متميزًا، حيث حققت كفاءة إزالة بلغت 99.13% خلال 60 دقيقة مع سعة امتزاز قصوى qe)) تبلغ 49.57 ملغم/غرام. تخضع آلية الامتزاز لتأثير تآزري من الروابط الهيدروجينية، وتفاعلات n→π، وتكوين معقدات سطحية. علاوة على ذلك، أظهر الطين النانوي قابلية ممتازة لإعادة الاستخدام، حيث حافظ على كفاءة إزالة بلغت 91.67% و82.59% في الدورتين الثانية والثالثة على التوالي، وتشير هذه النتائج إلى أن الطين النانوي الطبيعي حلا قابل للتطوير، وفعال من حيث التكلفة، وصديق للبيئة، لمعالجة الأصباغ والملوثات الصناعية.

المراجع

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التنزيلات

منشور

06/28/2026

كيفية الاقتباس

((تعيين الخواص الضوئية وقدرة الامتزاز، وكفاءة إعادة استخدام الطين النانوي الطبيعي لإزالة الصبغة المباشرة الأنيونية الملوثة للماء)) (ضيف الله م. ع. ح. & أحمد و. ع. أ.). (2026). المجلة العلمية لكلية التربيه جامعة ذمار, 15(1), 769 – 787. https://doi.org/10.60037/kjns1w90

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